丙氨酸席夫碱锰配合物对环己烯催化环氧化性能的研究  

The Epoxidation of Olefins with Molecular Oxygen Catalyzed by Alanine Schiff Base Complex (Sal-Ala-Mn)

作　　者：韩建萍[1] 赵继全[1] 张月成[1] 陆敬国[1] 

机构地区：[1]河北工业大学化工学院,天津300130

出　　处：《河北工业大学学报》2004年第4期80-83,共4页Journal of Hebei University of Technology

摘　　要：利用丙氨酸和水杨醛合成了席夫碱 Mn (Ⅲ) 配合物(Sal-Ala-Mn).以分子氧为氧源,异丁醛为共还原剂,研究了 Sal-Ala-Mn对环己烯氧化的催化性能,考察了温度、时间、催化剂量、异丁醛量、溶剂量对反应的影响.The Alanine schiff base was synthesized by the reaction of Alanine with salicylaldehyde first. Then it was used as a ligand to coordinate with Mn Ac to obtain a complex (Sal-Ala-Mn). The catalytic property of the 2 complex on the epoxidation of cyclohexene with molecular oxygen as the oxygen source and isobutyraldehyde as the co-reducing agent was studied. The influencing factors to the catalysis, including reaction temperature, reaction time, quantities of the catalyst and isobutyraldehyde, volume of solvent were investigated at the same time.

关 键 词：丙氨酸 席夫碱锰配合物 异丁醛 环己烯 环氧化 

分 类 号：O643.32[理学—物理化学]