四元配合物[Nd(C_4H_3OCOO)_2·NO_3·C_(10)H_8N_2]_2的合成与晶体结构  

Synthesis and Crystal Structure of [Nd(C_4H_3OCOO)_2·NO_3·C_(10)H_8N_2]_2 Complex

作　　者：李夏[1] 金琼花[1] 

机构地区：[1]首都师范大学化学系,北京100037

出　　处：《应用化学》2004年第10期1060-1062,共3页Chinese Journal of Applied Chemistry

基　　金：北京市自然科学基金项目(2022007);北京市科技新星项目(9528719800);北京市留学人员科技活动择优项目;教育部留学回国人员科研启动基金资助

摘　　要：The complex \ 2 Complex LI Xia *, JIN Qiong Hua (Department of Chemistry,Capital Normal University,Beijing 100037) Abstract The complex \[Nd(C 4 H 3 OCOO) 2 ·NO 3 ·C 10 H 8 N 2 \] 2 was synthesized from Nd(NO 3 ) 3 · n H 2 O, 2 furancarboxylic acid(C 4 H 3 OCOOH), and 2,2′ bipyridine(C 10 H 8 N 2 ). The unit cell is triclinic and of Pī symmetry. Unit cell parameters are:Pī, a =0 992 18(17) nm, b =1 023 05(17) nm, c = 1 114 4(3) nm , α =86 778(8)°, β =76 153(5)°, γ =70 363(14)°, M =584 58, V = 1 037 3(4) nm 3 , Z =1 , D calc = 1 877 Mg/m 3 , T =293(2) K. The final R =0 061 8, w R =0 164 4. Each Nd 3+ ion is coordinated by five O atoms of four furancarboxylate groups, two O atoms of nitrate and two N atoms of 2,2′ bipyridine molecule, with a coordination number of 9. The four carboxylate groups coordinate in two modes:bridging and bridging chelating . The two Nd 3+ ions in the dimer are held together by four carboxylate groups of furancarboxylic acid.The complex \ 2 Complex $$$$ LI Xia *, JIN Qiong Hua (Department of Chemistry,Capital Normal University,Beijing 100037) Abstract The complex \[Nd(C 4 H 3 OCOO) 2 ·NO 3 ·C 10 H 8 N 2 \] 2 was synthesized from Nd(NO 3 ) 3 · n H 2 O, 2 furancarboxylic acid(C 4 H 3 OCOOH), and 2,2′ bipyridine(C 10 H 8 N 2 ). The unit cell is triclinic and of Pī symmetry. Unit cell parameters are:Pī, a =0 992 18(17) nm, b =1 023 05(17) nm, c = 1 114 4(3) nm , α =86 778(8)°, β =76 153(5)°, γ =70 363(14)°, M =584 58, V = 1 037 3(4) nm 3 , Z =1 , D calc = 1 877 Mg/m 3 , T =293(2) K. The final R =0 061 8, w R =0 164 4. Each Nd 3+ ion is coordinated by five O atoms of four furancarboxylate groups, two O atoms of nitrate and two N atoms of 2,2′ bipyridine molecule, with a coordination number of 9. The four carboxylate groups coordinate in two modes:bridging and bridging chelating . The two Nd 3+ ions in the dimer are held together by four carboxylate groups of furancarboxylic acid.

关 键 词：钕 呋喃甲酸 联吡啶 混合配体配合物 晶体结构 

分 类 号：O631[理学—高分子化学]