1-(4-甲苯基)-2-(4-氨基苯基)乙烯的合成  

Synthesis of 1-(4-Methylphenyl)-2-(4-aminophenyl)ethylene

作　　者：李祥高[1] 王文保[1] 李蓉[1] 侯薇[1] 

机构地区：[1]天津大学化工学院精细化工系,天津300072

出　　处：《精细化工》2004年第8期563-566,共4页Fine Chemicals

基　　金：国家"863"计划资助项目(2002AA325050)~~

摘　　要：1 (4 甲苯基) 2 (4 氨基苯基)乙烯是合成苯乙烯基三芳胺类空穴传输材料的一种重要中间体。该文以4 甲基氯化苄与三苯基膦反应制备成Wittig试剂,再与4 硝基苯甲醛反应得到1 (4 甲苯基) 2 (4 硝基苯基)乙烯,然后经还原得到目的产物。通过考察还原剂、反应物浓度和反应时间对产物收率的影响得到最佳反应条件:温度95～100℃,n(铁粉)/n(硝基化合物)=5,硝基化合物浓度为0 27mol/L,反应时间为7h,收率达到78 6%。1-(4-Methylphenyl)-2-(4-aminophenyl)ethylene is one of the important intermediates for preparing hole transport materials of styryl triarylamines.In this paper,the objective compound was synthesized through the reaction of 4-nitrobenzaldehyde with the Wittig reagent prepared from 4-methylbenzyl chloride and triphenylphosphine and reduction of the resulting 1-(4-methylphenyl)-2-(4-nitrophenyl)ethylene.The influencing factors of reduction were studied and the optimum reaction conditions were obtained.Thus, the reaction was carried out at 95～100 ℃ for 7 h with n (Fe)/ n (nitro-compound)=5 and the nitro-compound of 0 .27 mol/L to get the highest yield of 78 .6%.

关 键 词：空穴传输材料 苯乙烯基三芳胺 还原 

分 类 号：TB34[一般工业技术—材料科学与工程]