PET/蒙脱土纳米复合材料的制备及其性能研究  

Study on Preparation and Properties of PET/Montmorillonite Nanocomposite

作　　者：袁茂全[1] 李明[1] 潘祥江[1] 

机构地区：[1]上海氯碱化工股份有限公司,上海200241

出　　处：《中国塑料》2004年第8期29-33,共5页China Plastics

摘　　要：将十六烷基三甲基溴化铵 /聚乙二醇混合物处理的蒙脱土与聚对苯二甲酸乙二醇酯在哈克流变仪上进行熔融复合 ,制备了聚对苯二甲酸乙二醇酯 (PET) /蒙脱土纳米复合材料。X射线衍射以及透射电镜分析表明 ,蒙脱土层间距明显增大 ,部分剥离并分散于PET基体中。对其力学性能和热性能的分析发现 ,当有机化蒙脱土用量为 5 %(质量含量 ,下同 )时 ,材料的热变形温度及弯曲模量分别达到 15 4℃和 3 .3 3 5GPa。Nanocomposites of polyethylene terephthalate (PET) and montmorillonite (MMT) were prepared via melt blending of PET with a mixture of cetyl ammonium and polyglycol treated MMT using a HAKKE rheometer.Wide angle X-ray diffraction and transmission electronic microscopy showed that the distance between the layers of montmorillonite was increased evidently and the montmorillonite was well dispersed in PET.When the content of the MMT was 5 %,a heat deformation temperature of 154 ℃ and a flexural modulus of 3.335 GPa of the nanocomposite were obtained.

关 键 词：聚对苯二甲酸乙二醇酯 蒙脱土 纳米复合材料 

分 类 号：TB383[一般工业技术—材料科学与工程]