羟基取代的多环芳烃与一氧化氮的反应研究  

Reaction of Hydroxy-substituted Polycyclic Aromatic Hydrocarbons with Nitric Oxide

作　　者：雷连娣[1] 张虹锐[1] 杨得锁[1] 吴隆民[1] 

机构地区：[1]兰州大学功能有机分子化学国家重点实验室

出　　处：《高等学校化学学报》2004年第10期1863-1865,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :2 0 0 72 0 13 )资助 .

摘　　要：The reaction of a series of hydroxy-substituted polycyclic aromatic hydrocarbons(PAHs)with nitric oxide containing trace O 2 was carried out in CH 2Cl 2 at room temperature. The products identified by IR, NMR and HRMS indicate that the mono nitration at para- or ortho-position with respect to hydroxy group on the benzene ring occurred regioselectively. The reactions are assumed to be initiated by single electron transfer and the reaction intermediates may be resonance stabilized phenoxy-like radicals.The reaction of a series of hydroxy-substituted polycyclic aromatic hydrocarbons(PAHs)with nitric oxide containing trace O 2 was carried out in CH 2Cl 2 at room temperature. The products identified by IR, NMR and HRMS indicate that the mono nitration at para- or ortho-position with respect to hydroxy group on the benzene ring occurred regioselectively. The reactions are assumed to be initiated by single electron transfer and the reaction intermediates may be resonance stabilized phenoxy-like radicals.

关 键 词：羟基取代 多环芳烃 一氧化氮 信使分子 

分 类 号：O625.15[理学—有机化学] O613.61[理学—化学]