[Mn(phen)_3](ClO_4)_2(H_2O)·05(azpy)的合成和晶体结构  

Synthesis and crystal structure of a novel manganese coordination compound[Mn(phen)_3](ClO_4)_2(H_2O)0.5(azpy)

作　　者：张聿平[1] 何雪雁[1] 陆新华[1] 于正风[1] 张勇[1] 李宝龙[1] 

机构地区：[1]苏州大学化学化工学院江苏省有机合成重点实验,江苏苏州215006

出　　处：《化学研究与应用》2004年第5期677-679,共3页Chemical Research and Application

基　　金：江苏省教学厅自然科学基金(No.03KJB150118);江苏省有机合成重点实验室基金资助项目

摘　　要：A new compound（ClO4）2（H2O）0.5（azpy）was synthesized.Its structure was determined by single X-ray diffraction.The crystal belongs to triclinic system,space group P1.The crystallographic data:a=11.813（2）,b=12.574（2）,c=14.580（3）*!,a=84.048（6）,β=77.878（15）,γ=67.902（12）°,V=1961.1（7）*!3,Z=2,F（000）=926,Mr=904.57,Dc=1.532Mg/m3,μ=0.542mm-1,R1=0.0770,and wR2=0.1373.In the ctystal Mn（Ⅱ）ion is coordinated with six nitrogen from three phen ligands to form a distorted octahedron geometry.A new compound(ClO_4)_2(H_2O)0.5(azpy)was synthesized.Its structure was determined by single X-ray diffraction.The crystal belongs to triclinic system,space group P1.The crystallographic data:a=11.813(2),b=12.574(2),c=14.580(3)*!,a=84.048(6),β=77.878(15),γ=67.902(12)°,V=1961.1(7)*!~3,Z=2,F(000)=926,Mr=904.57,Dc=1.532Mg/m^3,μ=0.542mm^(-1),R_1=0.0770,and wR_2=0.1373.In the ctystal Mn(Ⅱ)ion is coordinated with six nitrogen from three phen ligands to form a distorted octahedron geometry.

关 键 词：锰(Ⅱ)配合物 合成 晶体结构 邻菲咯啉 偶氮联吡啶 

分 类 号：O614[理学—无机化学]