双冠醚的研究 Ⅳ.仲胺型双冠醚及其聚合物的合成及表征  

STUDIES ON BIS CROWN ETHERS IV SYNTHESIS AND CHARACTERIZATION OF SECONDARY AMIEN TYPE BIS (4-BENZO-15-CROWN-5) S

作　　者：王德枌[1] 孙小强[1] 王登进[1] 段祥 

机构地区：[1]南京大学化学系

出　　处：《南京大学学报（自然科学版）》1989年第3期79-84,共6页Journal of Nanjing University（Natural Science）

基　　金：国家自然科学基金

摘　　要：六种用芳(杂)环桥联的席夫碱型双-(苯并15-冠-5)经硼氢化钠甲醇溶液还原制得六种新的仲胺型双(苯并15-冠-5),并用溶液萃取法比较了它们的络合性质. 使覆盖在SiO_2表面上的低分子量的环氧树脂与双冠醚2d的二氯甲烷溶液作用得到含有双冠醚结构单元的冠醚聚合物,并研究了后者对碱金属离子的络合容量.Six new secondary aminc type bis crown ethers with 15-crown-5 moieties bridged by an aromatic (hetero aromatic) ring were prepared by reduction of the corresponding Schiff bases. Their relative complexing powers with alkali metal picrates were compared by the solvent extraction method in a chloroform water system. Epoxy resin coated on the surface of a silica gel was treated with compoucd 2d in dichloromethanc to form a polymeric compoucd. The complexing capacity of the latter with alkali chloride was also stuied.

关 键 词：双冠醚 仲胺型 聚合物 席夫碱型 

分 类 号：O632.32[理学—高分子化学]