CH_3SH与简单自由基反应的研究现状  

The Present Studies on the Reaction of CH_3SH with Simple Radicals

作　　者：樊红敏[1] 曾艳丽[1] 孟令鹏[1] 郑世钧[1] 

机构地区：[1]河北师范大学计算量子化学研究所,河北石家庄050091

出　　处：《河北师范大学学报（自然科学版）》2004年第5期500-504,共5页Journal of Hebei Normal University：Natural Science

基　　金：河北省自然科学基金资助项目(B2004000147)

摘　　要：含硫有机化合物在对流层大气化学中起着重要的作用.目前在实验和理论上对CH3SH,CD3SH及CD3SD的反应进行了很多研究,主要集中在CH3SH与原子(O,H,F,Cl,Br等)、双原子分子和双原子自由基(NO,OH,OD,BrO,CN等)、三原子分子和自由基及多原子(O3,NO3等)的反应.本文中,笔者对CH3SH与原子和双原子自由基的反应进行了综述.Organic sulfide compounds play an important role in tropospheric chemistry,a lot of researches have been proceeded on the reaction of CH_3SH,CD_3SH and CD_3SD in experimented and theoretical chemistry recently.The researches focus on the reactions of CH_3SH with some single atoms(O,H,F,Cl,Br etc),some two-atom molecules and radicals (NO,OH,OD,BrO,CN etc),three-atom molecules and radicals (O_3,NO_3 etc) and many-atoms molecules and radicals.Some reactions of CH_3SH with single atoms and two-atom radicals were reviewed.

关 键 词：CH3SH 自由基 大气化学 氢抽提 速率常数 

分 类 号：P402[天文地球—大气物理学与大气环境] O613.51[天文地球—大气科学及气象学]