无皂微乳液法制备热固性双亲聚合物  

PREPARATION OF THERMAL SETTING AMPHIPHILIC POLYMER BY SOAP-FREE MICROEMULSION

作　　者：方治齐[1] 李志明 刘春华[1] 董其宝[1] 

机构地区：[1]合肥工业大学化工学院,安徽合肥230009 [2]合肥安默飞科技有限公司,安徽合肥230088

出　　处：《高分子材料科学与工程》2004年第5期70-72,76,共4页Polymer Materials Science & Engineering

摘　　要：以自制可聚合大分子表面活性剂HTP与丙烯酸酯类单体进行无皂微乳液五元共聚,制备可热固化双亲聚合物。讨论了微乳液形成的条件、聚合温度和水溶性丙烯酸酯类单体含量对双亲聚合物形态和结构的影响。Self-preparation polymerizable macromolecular surfactant HTP and acrylate monomer were used to prepare the amphiphilic polymer by soap-free microemulsion pentamer copolymerization. This amphiphilic polymer could be thermally set. The effects including forming microemulsion system condition, polymerization temperature and the content of water-soluble monomer on the morophology and structure of amphiphilic polymer were discussed.

关 键 词：无皂微乳液法 制备 热固性双亲聚合物 可聚合大分子表面活性剂 丙烯酸酯 甲基丙烯酸甲酯 丙烯酸丁酯 微乳液聚合 分子自组装 

分 类 号：TQ325.7[化学工程—合成树脂塑料工业]