硫脲类阴离子受体的研究进展  

Thiourea-based Receptors for Anion Recognition and Sensing

作　　者：吴芳英[1,2] 温珍昌[1] 江云宝[1] 

机构地区：[1]厦门大学化学系现代分析科学教育部重点实验室 [2]南昌大学化学系南昌330047

出　　处：《化学进展》2004年第5期776-784,共9页Progress in Chemistry

基　　金：国家自然科学基金 (2 0 1 75 0 2 0 );福建省自然科学基金 (D0 2 2 0 0 0 1 )项目

摘　　要：阴离子识别是超分子化学研究的重要内容之一 ,其关键环节是构筑可识别阴离子的结合受体 ,后者以非共价键力如静电作用、疏水作用、氢键等与阴离子结合。本文详细评述了近 5年来硫脲类阴离子识别受体的设计。Anion recognition and sensing have been developed into an important research subject in supramolecular chemistry. Noncovalent interactions such as hydrogen bonding, electrostatic interaction, hydrophobic interaction, etc. are the most important binding forces existing in the anion receptor binding complexes, which forms the basis of designing anion binding receptors. The design, construction and anion recognition and sensing of thiourea based receptors following mainly multi hydrogen bonding interactions are reviewed. 51 key references were cited to represent the related advances in the past 5 years.

关 键 词：硫脲衍生物 阴离子受体 超分子化学 阴离子识别 

分 类 号：O641.3[理学—物理化学] O623.663[理学—化学]