三(含氟烷基)磷酸酯的简便合成  

Convenient Synthesis of Triphosphate Fluoroalkyl Esters

作　　者：李战雄[1] 唐松青[1] 刘金涛[1] 钱国兴[1] 

机构地区：[1]中国科学院上海有机化学研究所

出　　处：《有机化学》2004年第10期1260-1261,共2页Chinese Journal of Organic Chemistry

摘　　要：以氯化锂催化四种含氟醇和三氯氧磷直接缩合分别得到了四种含氟三烷基磷酸酯 ,并以1HNMR ,19FNMR ,IR 。Using lithium chloride as catalyst, four tris(fluoroalkyl) phosphates were synthesized via condensation of fluorualcohol and phosphorus oxychloride directly. The structures of these phosphates were identified by H-1 NMR, F-19 NMR, IR, MS spectra and elemental analysis.

关 键 词：三(含氟烷基)磷酸酯 简便合成 氯化锂 含氟醇 三氯氧磷 催化 

分 类 号：TQ265.1[化学工程—有机化工]