水合羟基高氯酸镍髤的晶体结构(英文)  

Crystal Structure of the [nickel(Ⅱ)-(μ_3-hydroxide)-(μ_3-perchlorate)-aqua]_n Complex

作　　者：吴倩[1] 宋玉梅[1] 袁荣鑫[1] 熊仁根[1] 

机构地区：[1]南京大学配位化学研究所配位化学国家重点实验室,南京210093

出　　处：《无机化学学报》2004年第11期1375-1376,共2页Chinese Journal of Inorganic Chemistry

基　　金：国家重点基础研究发展规划资助项目(No.G2000077500);国家自然科学基金资助项目

摘　　要：Green single crystal of the title compound was accidentally obtained by the reaction of N,N′-bis(pyridylcarbonyl)-4,4′-diaminodiphenyl ether (L) with nickel perchlorate. In the structure of [Ni( ì3-OH)( ì3-ClO4)(H2O)]n, the local coordinating geometry around Ni center displays a distorted octahedron in which one coordination site of each metal atom was occupied by a water molecule. Each perchlorate anion and hydroxyl group acts as a tridentate bridging spacer to bind three Ni atoms, thus resulting in the formation of two-dimensional layered network. CSD: 414263.Green single crystal of the title compound was accidentally obtained by the reaction of N,N′-bis(pyridylcarbonyl)-4,4′-diaminodiphenyl ether (L) with nickel perchlorate. In the structure of [Ni( ì3-OH)( ì3-ClO4)(H2O)]n, the local coordinating geometry around Ni center displays a distorted octahedron in which one coordination site of each metal atom was occupied by a water molecule. Each perchlorate anion and hydroxyl group acts as a tridentate bridging spacer to bind three Ni atoms, thus resulting in the formation of two-dimensional layered network. CSD: 414263.

关 键 词：晶体结构 镍 羟基 高氯酸根 水合物 

分 类 号：O614.813[理学—无机化学]