一种含噁二唑基甲壳型聚合物的合成与表征  

SYNTHESIS AND CHARACTERIZATION OF A NEW MESOGEN-JACKETED POLYMER CONTAINING OXADIAZOLE

作　　者：范星河[1] 董红晨[1] 陈小芳[1] 宛新华[1] 周其凤[1] 

机构地区：[1]北京大学化学与分子工程学院高分子科学与工程系,北京100871

出　　处：《高分子学报》2004年第4期620-624,共5页Acta Polymerica Sinica

基　　金：国家自然科学基金项目资助项目 (基金号 2 0 13 40 10 );教育部科学研究重点项目资助项目 (项目号10 40 0 5 )

摘　　要：It is reported report herein the synthesis and characterization of a new mesogen-jacketed polymer containing an electron deficient oxadiazole unit __ poly{2,5-bis[(5-tert-butylphenyl)-1,3,4-oxadiazole]styrene} (BBPOS).BBPOS can be dissolved in THE,CHCl-3,xylene,and DMSO.The structure of the monomer and the polymer was confirmed by elemental analysis,NMR,MS and GPC.The optical and electronic properties of the polymer were investigated by UV-Vis absorption spectroscopy and photoluminescence spectroscopy.The results show that the polymer films emit greenish-blue light (λ max =390 nm) upon UV excitation.Thermo-analysis showed that the glass-transition temperature of the polymer is at 117℃.Moreover,its weight loss was less than 5% on heating to about 349℃ under nitrogen atmosphere.It is reported report herein the synthesis and characterization of a new mesogen-jacketed polymer containing an electron deficient oxadiazole unit - poly{2,5-bis[(5-tert-butylphenyl)-1,3,4-oxadiazole] styrene} (BBPOS). BBPOS can be dissolved in THE, CHCl3, xylene, and DMSO. The structure of the monomer and the polymer was confirmed by elemental analysis, NMR, MS and GPC. The optical and electronic properties of the polymer were investigated by UV-Vis absorption spectroscopy and photoluminescence spectroscopy. The results show that the polymer films emit greenish-blue light (lambda(max) = 390 nm) upon UV excitation. Thermo-analysis showed that the glass-transition temperature of the polymer is at 117 degreesC. Moreover, its weight loss was less than 5% on heating to about 349 degreesC under nitrogen atmosphere.

关 键 词：噁二唑 甲壳型聚合物 合成 电荷传输材料 电致发光材料 

分 类 号：O633[理学—高分子化学]