Prediction of Water Activity for Mixed Aqueous Solutions from the Data of Their Binary Constituent Solutions  

作　　者：刘艳升 徐春明 胡玉峰 严骏 

机构地区：[1]State Key Laboratory of Heavy Oil Processing, University of Petroleum, Beijing 102200, China [2]State Key Laboratory of Heavy Oil Processing, University of Petroleum, Beijing 102200, China High Pressure Fluid Phase Behavior & Property Research Laboratory, University of Petroleum, Beijing 102200,China [3]State Key Laboratory of Heavy Oil Processing, University of Petroleum, Beijing 102200, China High Pressure Fluid Phase Behavior & Property Research Laboratory, University of Petroleum, Beijing 102200,Chinahe equation of Patwardhan and Kumar for water activities of mixed electrolyte solutions is extended to aqueous solutions containing non-electrolytes. This equation and the linear isopiestic relation are used to predict water activities of 56 ternary aqueous solutions in terms of the data of their binary subsystems. Both equation of Patwardhan and Kumar and the linear isopiestic relation can provide good predictions for water activities of the present 40 electrolyte solutions, and the linear isopiestic relation generally yields better predictions. The predictions of the extended equation of Patwardhan and Kumar and the linear isopiestic relation are in general quite reasonable for the present 8 ternary solutions of electrolytes and non-electrolytes, and the results of the linear isopiestic relation are usually better. The predictions of these two methods generally agree well with the experimental data for the 8 non-electrolyte mixtures being studied, and the linear isopiestic relation is better.

出　　处：《Chinese Journal of Chemical Engineering》2004年第4期470-475,共6页中国化学工程学报（英文版）

基　　金：the National Natural Science Foundation of China (No. 20276037, No. 20006010).

摘　　要：The equation of Patwardhan and Kumar for water activities of mixed electrolyte solutions is extended to aqueous solutions containing non-electrolytes. This equation and the linear isopiestic relation are used to predict water activities of 56 ternary aqueous solutions in terms of the data of their binary subsystems. Both equation of Patwardhan and Kumar and the linear isopiestic relation can provide good predictions for water activities of the present 40 electrolyte solutions, and the linear isopiestic relation generally yields better predictions. The predictions of the extended equation of Patwardhan and Kumar and the linear isopiestic relation are in general quite reasonable for the present 8 ternary solutions of electrolytes and non-electrolytes, and the results of the linear isopiestic relation are usually better. The predictions of these two methods generally agree well with the experimental data for the 8 non-electrolyte mixtures being studied, and the linear isopiestic relation is better.The equation of Patwardhan and Kumar for water activities of mixed electrolyte solutions is extended to aqueous solutions containing non-electrolytes. This equation and the linear isopiestic relation are used to predict water activities of 56 ternary aqueous solutions in terms of the data of their binary subsystems. Both equation of Patwardhan and Kumar and the linear isopiestic relation can provide good predictions for water activities of the present 40 electrolyte solutions, and the linear isopiestic relation generally yields better predictions. The predictions of the extended equation of Patwardhan and Kumar and the linear isopiestic relation are in general quite reasonable for the present 8 ternary solutions of electrolytes and non-electrolytes, and the results of the linear isopiestic relation are usually better. The predictions of these two methods generally agree well with the experimental data for the 8 non-electrolyte mixtures being studied, and the linear isoniestic relation is better.

关 键 词：PREDICTION water activity aqueous mixed solution linear isopiestic relation the equation of Patward-han and Kumar 

分 类 号：O645[理学—物理化学]