无机固体酸催化合成橙花素  

SYNTHESIS OF NEROLIN BROMELIA CATALYZED BY INORGNIC SOLID ACID

作　　者：管仕斌[1] 俞善信[1] 文瑞明[2] 

机构地区：[1]湖南师范大学化学化工学院,湖南长沙410081 [2]湖南城市学院化学与环境工程系,湖南益阳413049

出　　处：《北京工商大学学报（自然科学版）》2004年第5期5-7,共3页Journal of Beijing Technology and Business University:Natural Science Edition

基　　金：湖南省教育厅科研基金资助项目(01C022)

摘　　要：在一水硫酸氢钠存在下,由β-萘酚和乙醇合成了橙花素(β-萘乙醚).研究了反应的影响因素和催化剂的重复使用性能,当β-萘酚、乙醇和硫酸氢钠的物质的量比为1∶4∶0.44,回流反应12h,醚收率达90.0%.结果表明:硫酸氢钠能够代替硫酸作为醚化催化剂.比较了六水三氯化铁、五水四氯化锡和一水硫酸氢钠催化合成橙花素的催化活性.Synthesized the nerolin bromelia (β-naphthyl ethyl ether) from β-naphthol and ethyl alcohol in the presence of sodium bisulfate monohydrate. Investigated the influent factors of reaction and reuse ability of the catalyst. The yield of the ether can reach 90.0% under amount of substance ratio of β-naphthol, ethyl alcohol and sodium bisulfate are 1∶4∶0.44, reflux reacting for 12 h. The result shows that sodium bisulfate can be used as catalyst for the etherification instead of sulfuric acid. Compared the catalytic activity of ferric chloride hexahydrate, stannic chloride pentahydrate and sodium bisulfate monohydrate for synthesis of nerolin bromelia.

关 键 词：橙花素 无机固体酸 一水硫酸氢钠 合成 酸催化 催化剂 回流反应 物质的量比 重复使用性能 四氯化锡 

分 类 号：TQ655[化学工程—精细化工] O643.36[理学—物理化学]