双吡唑啉酮类螯合剂1,6-双[4′-(1′-苯基-3′-甲基-5′-氧代)吡唑啉基]-1,6-己二酮与铀、钍固体配合物合成及表征  

Characteristic Studies on the Solid Coordinated Compounds of Uranium-Thorium with Chelating Agent 1,6-Bis [4'-(l'-phenyl-3'-methyl-5'-oxo) pyrazollnyl)-1, 6-hexane dione

作　　者：陈与德[1] 施宪法[1] 李思义[1] 徐迪民[1] 毛家骏[1] 傅磊[2] 杜慧芳[2] 

机构地区：[1]同济大学化学系,上海200092 [2]复旦大学物理二系,上海200433

出　　处：《化学学报》1993年第1期43-46,共4页Acta Chimica Sinica

摘　　要：本文报道了1,6.双[4′-(1′-苯基-3′-甲基-5′-氧代)吡唑啉基]-1,6-己二酮与铀、钍固体配合物的组成,从红外光谱、紫外吸收光谱、质子核磁共振谱、差热曲线及微分热重曲线的数据,得到了其配位状态方面信息。The characteristic study on the coordinated compounds of uranium-thorium with Ohelating Agent 1, 6-bis [4'-(1'-phenyl-3'-methyl-5'-oxo) pyrazol in yl]-1, 6-hexanedione (BPMOPH) is described. The structures of these coordinated compounds are confirmed with the analysis of IR, UV、NMR, DTA and DTG.

关 键 词：铀 钍 螯合剂 固体 络合物 

分 类 号：O614.62[理学—无机化学]