镧系乙酰丙酮-5,10,15,20-四(4-吡啶基)卟啉配合物  

Lanthanide Complexes of Acetylacetonate-meso-tetra(4-pyridyl) porphyrin

作　　者：刘国发[1] 马振清[1] 刘晓勋[1] 李冬妹[1] 

机构地区：[1]吉林大学化学系,长春130023

出　　处：《化学学报》1993年第8期791-795,共5页Acta Chimica Sinica

基　　金：国家自然科学基金

摘　　要：制备了乙酰丙酮-5,10,15,20-四(4-吡啶基)卟啉稀土配合物Ln(TPyP)acac[Ln:Dy,Ho,Yb, Lu;H_2TPy P:5,10,15,20-四(4-吡啶基)卟啉;Hacac:乙酰丙酮].配合物由一个中心稀土离子,一个乙酰丙酮和一个四(4-吡啶基)卟啉组成,乙酰丙酮以氧双齿配位,卟啉以氮四齿配位,因此配合物有六配位的结构.Lanthanide complexes of acetylacetonate-meso-tetra (4-pyridyl) porphyrin Ln (Tpyp)acac (Ln: Dy, Ho, Yb, Lu; H_2Tpyp: meso-tetra (4-pyridyl) porphyrin; Hacac: acetylacetone) were prepared by reaction of rare earth acetylacetonate complexes Ln (acac)_3·3H_2O with H_2Tpyp. The complexes consist of a centre ion of rare earth with one coordinated meso-tetra (4-pyridyl) porphyrin, and one acetylacetone. Their composition is LnC_(45)H_(31)N_8O_2. The free base porphyrin is coordinated in a tetradentate fashion, the acetylacetone is coordinated in a bidentate fashion. The rare earth ion in the complexes exhibits the coordination of six numbers.

关 键 词：乙酰丙酮 吡啶基 卟啉 镧系 配合物 

分 类 号：O614.33[理学—无机化学]