连续一级反应的热动力学研究  

THERMOKINETICS ON CONSECUTIVE FIRST ORDER REACTION

作　　者：王瑞林[1] 段治华[1] 邓郁[1] 胡兴无 

机构地区：[1]四川大学化学系,成都610064 [2]重庆科技情报所,重庆630013

出　　处：《化学研究与应用》1993年第2期35-39,共5页Chemical Research and Application

基　　金：国家自然科学基金

摘　　要：本文把时间比法引入热动力学研究,建立了连续一级反应的热动力学研究法,并用来研究了一个连续反应体系的热动力学,验证了该方法的正确性.The method of time ratio was introduced to thermokinetics research, so the thermokinetic method on consecutive first order reaction was suggested. This method was then used to study the alkaline hydrolysis of diethyl phthalate in 50% aq. CH_3CN. The rate constants of this reaction calculted are in agreement with values in the literature.

关 键 词：连续反应 热动力学 邻苯二甲酸酯 

分 类 号：O623.624[理学—有机化学]