纳米TiO_2膜修饰电极上对硝基苯甲酸异相电催化还原  

Heterogeneous Electrocatalytic Reduction of p-Nitrobenzoic Acid on Nanocrystalline TiO_2 Film Modified Electrode

作　　者：褚道葆[1] 姚文俐[1] 顾家山[1] 李晓华[1] 沈广霞[2] 

机构地区：[1]安徽师范大学化学与材料科学学院,芜湖241000 [2]厦门大学化学系,厦门361005

出　　处：《高等学校化学学报》2004年第11期2137-2139,共3页Chemical Journal of Chinese Universities

基　　金：安徽省自然科学基金 (批准号 :0 0 0 45 3 17);安徽省高校科研基金 (批准号 :2 0 0 3 kj13 1;2 0 0 4kj164 zd)资助

摘　　要：Redox behavior and electrocatalytic activities of the Ti/nano\|TiO\-2 electrode were investigated by cyclic voltammetry(CV) and bulk electrolysis. The results indicate that there are two pairs of well\|defined redox peaks for Ti/nano\|TiO\-2 film electrode in the 1 mol/L H\-2SO\-4 and 1 mol/L NaOH at 0.1 V/s corresponding to TiO\-2/ Ti\-2O\-3 and TiO\-2/Ti(OH)\-3 reversible electrode process. In 1 mol/L NaOH medium the peak potential evidently shift to the negative value with \%E\%\+r\-\{1/2\} being -1.38 and -1.72 V(\%vs\%.SCE), and the heterogeneous electrocatalytic reduction activities of TiO\-2/Ti\-2O\-3 redox for \%p\%\|nitrobenzoic acid (PNA) is very high. The indirect electroreduction of PNA to \%p\%\|aminobenzoic acid (PAA) by Ti\+Ⅳ/Ti\+Ⅲ redox system on nanocrystalline TiO\-2 film surface was found, and the electrode reaction mechanism is called electro\|catalytic(EC) mechanism. In the preparative electrolysis, the current efficiency was over 90%.Redox behavior and electrocatalytic activities of the Ti/nano\|TiO\-2 electrode were investigated by cyclic voltammetry(CV) and bulk electrolysis. The results indicate that there are two pairs of well\|defined redox peaks for Ti/nano\|TiO\-2 film electrode in the 1 mol/L H\-2SO\-4 and 1 mol/L NaOH at 0.1 V/s corresponding to TiO\-2/ Ti\-2O\-3 and TiO\-2/Ti(OH)\-3 reversible electrode process. In 1 mol/L NaOH medium the peak potential evidently shift to the negative value with \%E\%\+r\-\{1/2\} being -1.38 and -1.72 V(\%vs\%.SCE), and the heterogeneous electrocatalytic reduction activities of TiO\-2/Ti\-2O\-3 redox for \%p\%\|nitrobenzoic acid (PNA) is very high. The indirect electroreduction of PNA to \%p\%\|aminobenzoic acid (PAA) by Ti\+Ⅳ/Ti\+Ⅲ redox system on nanocrystalline TiO\-2 film surface was found, and the electrode reaction mechanism is called electro\|catalytic(EC) mechanism. In the preparative electrolysis, the current efficiency was over 90%.

关 键 词：纳米TiO2膜电极 电催化 循环伏安 对硝基苯甲酸 对氨基苯甲酸 

分 类 号：O646.5[理学—物理化学]