β-CD存在下MMA细乳液体系的RAFT聚合  

Methyl Methacrylate Miniemulsion Polymerization via RAFT Mechanism Using β-Cyclodextrin as Solubilizer

作　　者：邵亚军[1] 倪沛红[1] 纪晓丽[1] 余樟清[1] 

机构地区：[1]苏州大学化学化工学院

出　　处：《高等学校化学学报》2004年第11期2176-2178,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :2 0 2 760 44 )资助

摘　　要：The methyl methacrylate(MMA) reversible addition-fragmentation chain transfer(RAFT) miniemulsion polymerization in the presence of β-cyclodextrin(β-CD) was investigated. β-CD is found to act both as an efficient solubilizer for RAFT agent(2-cyanopro-2-yl dithiobenzoate) and as a stabilizer for heterogeneous polymerization. The RAFT miniemulsion polymerizations with or without β-CD were compared in terms of kinetics and the molecular weight distribution. The problem of poor latex stability was observed in this system. A good result of the control over RAFT miniemulsion polymerization of MMA was obtained with β-CD. The increase of the molecular weight of poly(methyl methacrylate) shows a linear relationship with the monomer conversion. The polydispersity index of the polymer with β-CD(PDI=1.18—1.21) is smaller than that without β-CD. TEM photographs showed that the PMMA particles produced with β-CD had smooth surfaces and uniform particle size. Higher amount of sodium dodecyl sulfate and hexadecane was found in favor of improving the controllability of the system. Oil soluble initiator is beneficial to the controllability of the polymerization.The methyl methacrylate(MMA) reversible addition-fragmentation chain transfer(RAFT) miniemulsion polymerization in the presence of β-cyclodextrin(β-CD) was investigated. β-CD is found to act both as an efficient solubilizer for RAFT agent(2-cyanopro-2-yl dithiobenzoate) and as a stabilizer for heterogeneous polymerization. The RAFT miniemulsion polymerizations with or without β-CD were compared in terms of kinetics and the molecular weight distribution. The problem of poor latex stability was observed in this system. A good result of the control over RAFT miniemulsion polymerization of MMA was obtained with β-CD. The increase of the molecular weight of poly(methyl methacrylate) shows a linear relationship with the monomer conversion. The polydispersity index of the polymer with β-CD(PDI=1.18—1.21) is smaller than that without β-CD. TEM photographs showed that the PMMA particles produced with β-CD had smooth surfaces and uniform particle size. Higher amount of sodium dodecyl sulfate and hexadecane was found in favor of improving the controllability of the system. Oil soluble initiator is beneficial to the controllability of the polymerization.

关 键 词：Β-CD RAFT聚合 细乳液聚合 甲基丙烯酸甲酯(MMA) 

分 类 号：O631.5[理学—高分子化学]