掺铒氧氟碲酸盐玻璃的上转换发光研究  

Upconversion Luminescence Research of Er^(3+)-doped Oxyfluoride Tellurite Glasses

作　　者：徐时清[1] 张军杰[1] 戴世勋[1] 孙洪涛[1] 胡丽丽[1] 姜中宏[1] 

机构地区：[1]中国科学院上海光学精密机械研究所

出　　处：《无机材料学报》2004年第6期1415-1418,共4页Journal of Inorganic Materials

基　　金：国家自然科学基金(60207006);上海市光科技项目(02261046);上海青年科技启明星项目(04QMX 1448)

摘　　要：研究了掺铒氧氟碲酸盐玻璃的吸收光谱和上转换发光光谱,分析了Er3+离子在氧氟碲酸盐玻璃中的上转换发光机理.结果表明:通过975nm的激光二极管(LD)激发,在室温下同时观察到强烈的绿光(524和545nm)和红光(655nm),分别是由于Er3+离子2H(11/2)→4I(15/2),4S(3/2)→4I(15/2),和4F(9/2)→4I(15/2)跃迁.随PbF2含量增加,绿光的发光强度增加趋势较小,而红光的发光强度增加趋势大于绿光.上转换发光机理主要涉及能量转移和激发态吸收,强烈的绿光和红光激发都是由于双光子吸收过程.The absorption spectra and upconversion luminescence spectra of Er3+-doped oxyfluoride tellurite glasses were investigated, and upconversion luminescence mechanisms of Er3+ in oxyfluoride tellurite glasses were analyzed. The results show that the intense green (524 and 545nm) and red (655nm) emissions corresponding to the H-2(9/2) --> I-4(15/2), H-2(11/2) --> I-4(15/2), S-4(3/2) --> I-4(15/2), and F-4(9/2) --> I-4(15/2) transitions of Er3+ ions, respectively, can be simultaneously observed at room temperature under 975 nm diode laser excitation. With increasing PbF2 concentrations, the intensity for the green emissions increases slightly, while the red emission intensity enhances much larger than the green emission intensities. There are two basic upconversion mechanisms: excited state absorption and energy transfer, and a two-photon upconversion process is assigned to the intense green and red emission, respectively.

关 键 词：氧氟碲酸盐玻璃 光谱性质 上转换发光 Er^3+离子 

分 类 号：TQ171[化学工程—玻璃工业]