A Novel Borophosphate Coordination Polymer with Sandwich-type Supramolecular Architecture  

作　　者：MaoFengLI HengZhenSHI YongKuiSHAN MingYuanHE 

机构地区：[1]DepartmentofChemistryEastChinaNormalUniversity,Shanghai200062 [2]DepartmentofPhysicsEastChinaNormalUniversity,Shanghai200062

出　　处：《Chinese Chemical Letters》2004年第7期863-866,共4页中国化学快报（英文版）

摘　　要：A novel borophosphate (Hmel)3{Co2[(mel)2(HPO4)2(PO4)]·H3BO3·H2O} (mel= melamine) has been synthesized under mild solvothermal conditions. The structure of the compound exists a high ordered organic-inorganic sandwich-type supramolecular architecture via metal-coordination, hydrogen bonds and π-π stacking interactions.A novel borophosphate (Hmel)3{Co2[(mel)2(HPO4)2(PO4)]·H3BO3·H2O} (mel= melamine) has been synthesized under mild solvothermal conditions. The structure of the compound exists a high ordered organic-inorganic sandwich-type supramolecular architecture via metal-coordination, hydrogen bonds and π-π stacking interactions.

关 键 词：BOROPHOSPHATE coordination polymer supramolecular architecture solvothermal. 

分 类 号：O613.81[理学—无机化学] O641.3[理学—化学]