Study on Synthesis and Intercalation Behavior of Layered Zirconium Proline-N-methylphosphonate-phosphate  

作　　者：XiaoPingRAO XiangKaiFU KaiRAO 

机构地区：[1]CollegeofChemistryandChemicalEngineering,South-WestChinaNormalUniversity,Chongqing400715

出　　处：《Chinese Chemical Letters》2004年第7期871-874,共4页中国化学快报（英文版）

摘　　要：Zirconium proline-N-methylphosphonate-phosphate (α-ZPMPP) was prepared in the presence of HF for the first time. The a-ZPMPP sample is highly crystallized with interlayer distance of 1.52 nm. The interlayer distance of complex of α-ZPMPP with n-butylamine (α-ZPMPP-BA) is in 0.45 nm larger than that of α-ZPMPP. The α-ZPMPP possesses different intercalation behavior of host-guest compound from α-ZP.Zirconium proline-N-methylphosphonate-phosphate (α-ZPMPP) was prepared in the presence of HF for the first time. The a-ZPMPP sample is highly crystallized with interlayer distance of 1.52 nm. The interlayer distance of complex of α-ZPMPP with n-butylamine (α-ZPMPP-BA) is in 0.45 nm larger than that of α-ZPMPP. The α-ZPMPP possesses different intercalation behavior of host-guest compound from α-ZP.

关 键 词：Zirconium proline-N-methylphosphonate-phosphate N-BUTYLAMINE intercalation complex interlayer distance host-guest compound. 

分 类 号：O627.43[理学—有机化学]