难互溶Cu-Fe系机械合金化的高分辨电镜研究  

HIGH RESOLUTION ELECTRON MICROSCOPIC STUDY OF IMMISCIBLE Cu-Fe SYSTEM DURING MECHANICAL ALLOYING

作　　者：吴玉琨[1] 黄建宇[1] 何安强 胡魁毅 孟祥敏[1] 

机构地区：[1]中国科学院金属研究所固体原子象实验室,沈阳110015

出　　处：《金属学报》1993年第12期B545-B552,共8页Acta Metallurgica Sinica

基　　金：国家自然科学基金

摘　　要：机械合金化可使室温下几乎不互溶体系Cu_xFe_(100-x)形成过饱和固溶体fcc相区的固溶度范围扩展到x>35 at-%.对Cu_(40)Fe_(60)进行的高分辨电镜观察表明:球磨3h后bcc相与fcc相之间存在N-W关系,即<001>α∥<110>γ。,<110>α∥<111>γ,表明在球磨的过程中发生了逆马氏体相变,fcc相区的扩展与此密切相关.球磨60h后形成了尺寸比较均匀的纳米晶结构.高分辨电镜同时观察到了粒子的破断。Supersaturated solid solutions have been obtained by mechanical alloying inCu-Fe system which are immiscible at room temperature. The fcc phase range has been ex-tended to x>35 at.-% Cu. High resolution electron microscope images show that thereexist N-W orientation relationship,i.e. < 001 > α//<110>γ and < 110 > α// < 111 > γbetween bcc phase and fcc phase after 3h milling. It is quite possible that inverse martensitictransformation has occurred during mechanical alloying and the extension of fcc phase rangeclosely relates to this transformation. The fracture and refinement of particles, and cold-weld-ing images were also observed by using a high resolution electron microscope. After 60h me-chanical alloying, homogenous nanocrystals with particle size about 10 nm formed.

关 键 词：Cu-Fe系 机械合金化 电镜观察 

分 类 号：TG11[金属学及工艺—物理冶金]