Novel Chiral Ferrocenyl Aziridino Alcohol Catalysts Promoting Asymmetric Addition of Diethylzinc to Aldehydes  

作　　者：王敏灿 王德坤 娄建平 华远照 

机构地区：[1]Department of Chemistry, Zhengzhou University, Zhengzhou, Henan 450052, China

出　　处：《Chinese Journal of Chemistry》2004年第6期512-514,共3页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China (No. 20172047); Henan Outstanding Youth Program 2001; and the Education Department of Henan Province.

摘　　要：Optically active aziridino alcohols containing ferrocenyl groups were prepared from commercially available L-threonine in excellent yields and used as catalysts to promote the asymmetric addition of diethylzinc to aryalde-hydes to afford 1-arylpropanol in up to 84% enantiomeric excesses with moderate to good yields.Optically active aziridino alcohols containing ferrocenyl groups were prepared from commercially available L-threonine in excellent yields and used as catalysts to promote the asymmetric addition of diethylzinc to aryalde-hydes to afford 1-arylpropanol in up to 84% enantiomeric excesses with moderate to good yields.

关 键 词：ferrocenyl aziridino alcohol catalyst asymmetric addition 

分 类 号：O643.3[理学—物理化学]