A Novel Debromination of vic-Dibromides to Alkenes with InCl_3(cat.)/Sm System in Aqueous Media  

A Novel Debromination of vic-Dibromides to Alkenes with InCl_3(cat.)/Sm System in Aqueous Media

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作  者:王敏 王磊 李品华 晏金灿 

机构地区:[1]Department of Chemistry, Huaibei Coal Teachers College [2]State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

出  处:《Chinese Journal of Chemistry》2004年第8期863-866,共4页中国化学(英文版)

基  金:Project supported by the National Natural Science Foundation of China (Nos. 20372024 and 20172018); the Excellent Scientist Foundation of AnhuiProvince (No. 2001040); the Natural Science Foundation of the Education Department of Anhui Province (No. 2

摘  要:A novel debromination of vic-dibromides to alkenes with InCl3(cat.)/Sm system in aqueous media has been de- veloped. The reaction gives the E-isomers with excellent yields.A novel debromination of vic-dibromides to alkenes with InCl3(cat.)/Sm system in aqueous media has been de- veloped. The reaction gives the E-isomers with excellent yields.

关 键 词:DEBROMINATION vic-dibromide ALKENE indium trichloride samarium metal aqueous media 

分 类 号:O621[理学—有机化学]

 

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