Fluorescence and cofluorescence enhancement of Tb(Ⅲ) complexes with pyromellitic acid by M (M = Gd, La, Ca, and Sr ions)  

作　　者：WANGZhengxiang CHENHong SHUWangen ZHAODongbai ZHOUZhongcheng 

机构地区：[1]CollegeofChemistryandChemicalEngineering.CentralSouthUniversity.Changsha410083,China／KeyLaboratoryofNewMaterialsandTechnologyofChinaNationalPackagingCorporation.ZhuzhouInstituteofTechnology,Zhuzhou412008,China [2]KeyLaboratoryofNewMaterialsandTechnologyofChinaNationalPackagingCorporation,ZhuzhouInstituteofTechnology,Zhuzhou412008,China [3]CollegeofChemistryandChemicalEngineering.CentralSouthUniversity,Changsha410083,China

出　　处：《Rare Metals》2004年第1期32-37,共6页稀有金属（英文版）

基　　金：This work is financially supported by the Natural Science Foundation of Hunan Province (No. 01JJY3004); and Technology of China National Packaging Corporation.

摘　　要：Fluorescence and cofluorescence properties of Tb(Ⅲ) solid complexes werestudied using pyromellitic acid (PMA) as ligand and fluorescence inert ions as doping elements. Thecofluorescence enhancement, a result of ligand sensitized fluorescence, was observed in Tb(Ⅲ) solidcomplexes doped with fluorescent inert ions La(Ⅲ), Gd(Ⅲ), Ca(Ⅲ), and Sr(Ⅲ). The effect of thetype and content of doping elements on fluorescence enhancement was studied, and optimum conditionswere determined. The results show that Gd (La, Ca, Sr) has clear cofluorescence effect in solidcomplex Tb-M-PMA system, and in present work, rare earth complex fluorescent powder that emitsbright green fluorescence at ultraviolet excitation was obtained, which had potential application asfluorescent anti-counterfeit ink.Fluorescence and cofluorescence properties of Tb(Ⅲ) solid complexes werestudied using pyromellitic acid (PMA) as ligand and fluorescence inert ions as doping elements. Thecofluorescence enhancement, a result of ligand sensitized fluorescence, was observed in Tb(Ⅲ) solidcomplexes doped with fluorescent inert ions La(Ⅲ), Gd(Ⅲ), Ca(Ⅲ), and Sr(Ⅲ). The effect of thetype and content of doping elements on fluorescence enhancement was studied, and optimum conditionswere determined. The results show that Gd (La, Ca, Sr) has clear cofluorescence effect in solidcomplex Tb-M-PMA system, and in present work, rare earth complex fluorescent powder that emitsbright green fluorescence at ultraviolet excitation was obtained, which had potential application asfluorescent anti-counterfeit ink.

关 键 词：fluorescence enhancement COFLUORESCENCE doping elements TERBIUM pyromellitic acid 

分 类 号：O614.341[理学—无机化学] O641.4[理学—化学]