高分辨气相色谱/质谱法分析新闻纸和复印纸中的二噁  

Determination of Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans in Newsprintsand Copy Papers by HRGC/HRMS

作　　者：张青[1] 杨志军[1] 陈吉平[1] 吴文忠[1] 梁鑫淼[1] 卢佩章[1] 

机构地区：[1]中国科学院大连化学物理研究所,辽宁大连116012

出　　处：《色谱》2004年第4期449-451,共3页Chinese Journal of Chromatography

摘　　要：随机选择空白的和经过印刷的新闻纸和复印纸 ,粉碎后用溶剂提取并经多步色谱柱纯化 ,采用同位素稀释、高分辨气相色谱 /高分辨质谱 (HRGC/HRMS)联用技术分析了其中的二含量。结果表明 :新闻纸中二的总量高于复印纸 ,但是毒性当量却低于复印纸 ;经过印刷的新闻纸和复印纸中二的含量均高于空白的新闻纸和复印纸 ;新闻纸和复印纸中相同二异构体的含量是不同的。空白的和经过印刷的新闻纸中二毒性当量分别为 0 4 8ng/kg和 0 6 1ng/kg,而空白的和经过印刷的复印纸中二毒性当量分别为 0 74ng/kg和 0 79ng/kg。所有样品中添加的13 C标记的 2 ,3,7,8位取代的二回收率均在 4 9 82 %至 131 34%之间。The concentrations of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) in newsprints and copy papers which included blank and printed paper samples were determined by isotope dilution and high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS). All of the paper samples collected at random were extracted with organic solvents and the extracts were cleaned up successively by three different chromatographic columns. The results indicated that the total concentrations of PCDD/Fs in newsprints were higher than those in copy papers, but the total toxicity equivalent (TEQ) values of newsprint samples were lower than those in copy paper samples. In addition, for both papers, the concentrations of PCDD/Fs in printed papers were higher than the blank papers. Moreover, the patterns of PCDD/Fs in newsprint samples and copy paper samples were different. The total international TEQ values of PCDD/Fs in newsprints and printed newsprints were 0.48 (ng/kg) and 0.61 (ng/kg), respectively. Moreover, the total TEQ values of PCDD/Fs in copy paper and printed copy paper samples were 0.74 (ng/kg) and 0.79 (ng/kg), respectively. The recoveries of ()^(13)C labeled 2,3,7,8-substituted PCDD/Fs spiked before extraction into all paper samples were between 49.82% and 131.34%.

关 键 词：高分辨气相色谱 质谱 多氯代二苯并二噁英 呋喃 新闻纸 复印纸 

分 类 号：O658[理学—分析化学]