固相反应合成丙二胺合钴氧合性能的研究  

Oxygenation of Propane Diamine Cobalt(II) Complexes Synthesized via Solid State Reaction

作　　者：杨红伟[1] 岳凡[1] 陈玲[1] 封顺[1] 王吉德[1] 刘爱华[1] 陈华梅[1] 

机构地区：[1]新疆大学化学化工学院,乌鲁木齐830046

出　　处：《无机化学学报》2004年第12期1421-1425,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.29962003)

摘　　要：Eight Complexes were synthesized with propane diamine and cobalt with four different ions under the reaction of liquid-solid and solid-gas, respectively. After reacted with O2, they are characterized with elemental analysis, IR, XRD, thermogravimetric analysis. Their ability to bind O2 was studied with gas volume try. As a result, it is found that the ability to bind O2 was related to cobalt salt with different ions, and the types of synthesize methods due to different r eaction mechanism.Eight Complexes were synthesized with propane diamine and cobalt with four different ions under the reaction of liquid-solid and solid-gas, respectively. After reacted with O2, they are characterized with elemental analysis, IR, XRD, thermogravimetric analysis. Their ability to bind O2 was studied with gas volume try. As a result, it is found that the ability to bind O2 was related to cobalt salt with different ions, and the types of synthesize methods due to different r eaction mechanism.

关 键 词：固相反应合成 丙二胺 钴配合物 氧合性能 氧载体 

分 类 号：O614.812[理学—无机化学]