双核配合物[Cu_2(L-Asp)(phen)_3(NO_3)](NO_3)·4H_2O的合成及晶体结构  

Synthesis and Crystal Structure of Binuclear Complex [Cu_2(L-Asp)(phen)_3(NO_3)](NO_3)·4H_2O

作　　者：马录芳[1] 梁福沛[1] 覃海错[1] 胡瑞祥[1] 张漫波[1] 郁开北[2] 

机构地区：[1]广西师范大学化学化工学院 [2]中科院成都有机所分析测试中心,成都610041

出　　处：《无机化学学报》2004年第12期1429-1432,共4页Chinese Journal of Inorganic Chemistry

基　　金：广西自然科学基金资助项目(No.9912044)

摘　　要：The new complex [Cu2(L-Asp)(phen)3(NO3)](NO3)·4H2O (L-Asp=L-aspartic acid and phen=1,10-phenanthroline) has been synthesized and its crystal structure ha s been determined. The complex crystallizes in the monoclinic with space group P 21/c, The cell parameters are: a=1.261 3(2) nm, b=1.500 8(4) nm, c=2.230 7(4) nm , 穋m-3. The complex contains tw o six-coordinated copper ions, and these two copper ions are connected together by L-aspartate to give rise to a binuclear structure. Hydrogen bondsThe new complex [Cu2(L-Asp)(phen)3(NO3)](NO3)·4H2O (L-Asp=L-aspartic acid and phen=1,10-phenanthroline) has been synthesized and its crystal structure ha s been determined. The complex crystallizes in the monoclinic with space group P 21/c, The cell parameters are: a=1.261 3(2) nm, b=1.500 8(4) nm, c=2.230 7(4) nm , 穋m-3. The complex contains tw o six-coordinated copper ions, and these two copper ions are connected together by L-aspartate to give rise to a binuclear structure. Hydrogen bonds and

关 键 词：双核配合物 铜配合物 合成 晶体结构 天冬氨酸 

分 类 号：O614.121[理学—无机化学] O629.711[理学—化学]