球形ZnS纳米粒子的制备和光学性质  

Preparation and Optical Properties of Spherical ZnS Nanoparticles

作　　者：汤浩[1] 徐国跃[1] 吴茹菲[1] 李莹滢[1] 吕兆萍[1] 

机构地区：[1]南京航空航天大学材料科学与技术学院,南京210016

出　　处：《南京航空航天大学学报》2004年第6期778-783,共6页Journal of Nanjing University of Aeronautics & Astronautics

基　　金：国防基础科研基金 (J1 3 0 0 A0 0 2 )资助项目 ;航空科学基金 (0 3 G5 2 0 60 )资助项目

摘　　要：用快速均匀沉淀法制备了平均粒径 3 nm左右的球形 Zn S纳米粒子。并且讨论了成长时间 ,反应温度 ,体系p H值 ,反应物浓度和配比对 Zn S纳米粒子尺寸的影响。通过 XRD,BET,紫外可见吸收光谱表征了 Zn S纳米粒子的尺寸、结构和表面态性质。通过红外吸收光谱证明了吸附在 Zn S纳米颗粒上的乙酸基起到控制粒子长大和防止团聚的作用。研究了 Zn S纳米晶粒的荧光光谱 ,证实其在 42 5 nm处的蓝色发光峰是来源于表面硫空位与锌空位之间的电子 -空穴复合跃迁发光。Nanoparticles of zinc sulphide with average size about 3 nm, are synthesized by a chemical method for quick homogeneous precipitation. The effects of preparation parameter on ZnS particles such as reaction temperature, growth time, pH condition, concentration are discussed. XRD, BET and UV-V absorption are used to characterize the size, structure and surface states of ZnS nanoparticles. The FTIR spectrum of ZnS nanoparticles demonstrates that the acetic ions, absorbed on the surface of nanoparticles can control the growth and avoid the aggregation of particles. Photoluminescence measurements show that the peak at 425 nm in the photoluminescence emission specturm of ZnS is attributed to the electron-hole recombination from surface vacancies to Zn and S atoms. The nanoparticles provide a suitable semiconductor nanocluster for optoelectronic and a phosphor suitable for flat display technology.

关 键 词：ZNS纳米粒子 快速均匀沉淀法 光谱 

分 类 号：O614.24[理学—无机化学]