β-萘乙醚的微波合成研究  

Study on the synthesis of β-naphthyl ethyl ether under microwave radiation

作　　者：赵胜芳[1] 陈年友[1] 明键伟[1] 王菊平[1] 孙国建[1] 

机构地区：[1]黄冈师范学院化学系,湖北黄冈438000

出　　处：《应用化工》2004年第6期25-27,共3页Applied Chemical Industry

基　　金：湖北省教育厅重点科研资助基金项目(1999A083;2002A04002)

摘　　要：研究了以β 萘酚、无水乙醇为原料,浓硫酸为催化剂,采用微波辐射方法合成β 萘乙醚,并探索了反应条件对产物产率的影响。实验结果表明,在反应物用量β 萘酚3.6g(0.025mol),无水乙醇30mL,浓硫酸7mL,微波辐射功率260W,微波辐射时间40min条件下反应,产率可达71%以上。与常规加热合成方法比较,本方法反应时间大大缩短(由6h缩至40min),产率较高(从60%增至71%)。This paper studies the synthesis of β-naphthyl ethyl ether under microwave radiation with β-naphthol and anhydrous alcohol as raw material and concentrated sulfuric acid as catalyst. It also explores the effects of reaction condition upon the yields. The experimental results show that β-naphthol is 3.6 g(0.025 mol),anhydrous alcohol is 30 mL,concentrated sulfuric acid is 7 mL,the microwave radiation power is 260 W,radiation time is 40 min,the yield of β-naphthyl ethyl ether exceed 71%. Using this method instead of the original methods,the reaction time can be shorted(from 6h to 40 min)and the yield be increased(from 60% to 71%).

关 键 词：Β-萘乙醚 微波辐射 反应条件 合成 

分 类 号：O625[理学—有机化学]