手性相转移催化剂的设计与催化性能比较  

The Design of Chiral Phase-transfer Catalyst and Comparison of Their Asymmetric Catalytic Capability

作　　者：张占辉[1] 

机构地区：[1]河北师范大学化学学院,河北石家庄050091

出　　处：《河北师范大学学报（自然科学版）》2004年第6期608-614,共7页Journal of Hebei Normal University：Natural Science

基　　金：河北省自然科学基金资助项目(202140)

摘　　要：介绍了近几年设计的手性相转移催化剂,包括手性季铵盐、季钅盐、手性冠醚、金属配合物等,并以二苯亚胺甘氨酸叔丁酯的不对称烷基化反应为模板,对它们的催化性能进行了比较.The research progress in the area of newly designed chiral phase-transfer catalysis such as chiral quaternary ammonium,chiral quaternary phosphonium,chiral crow ether and chiral salen complexes was reviewed.Their asymmetric catalytic capability was compared based on the enantioselective alkylation of N-(diphenylmethylene)glycine tert-butyl ester.

关 键 词：手性相转移催化剂 催化性能 金属配合物 亚胺 烷基化反应 手性冠醚 季铵盐 甘氨酸叔丁酯 季鏻盐 不对称 

分 类 号：O621.251[理学—有机化学] O643[理学—化学]