水化学对Zr-4合金氧化膜形貌的影响  

Effect of Water Chemistry on Oxide Morphologies of Zircaloy-4

作　　者：刘文庆[1] 陈文觉[1] 李强[1] 周邦新[1] 姚美意[1] 

机构地区：[1]上海大学材料研究所,200072

出　　处：《核动力工程》2004年第6期517-521,共5页Nuclear Power Engineering

基　　金：国家自然科学基金资助(批准号:50171039和50301009)

摘　　要：为了研究LiOH水溶液影响Zr-4合金耐腐蚀性能的机理,用扫描电子显微镜和扫描探针显微镜观察Zr-4合金样品在不同介质中腐蚀后氧化膜内外表面的形貌。实验结果表明:由于氧化过程体积膨胀,氧化膜中存在平行于界面的压应力。在压应力的作用下,氧化膜向外鼓起,并在垂直于平面的方向上产生张应力,导致氧化膜破裂,从而使腐蚀加速。LiOH水溶液浓度越高,这个过程越快。To understand the degradation behavior of corrosion resistance in LiOH aqueous solution for Zircaloy-4, Scanning Electron Microscope (SEM) and Scanning Probe Microscope (SPM) are performed to observe the inside and outside surface morphologies of the oxide. Based on the results, it is suggested that there exists compressive stress parallel to oxide/matrix interface in the oxide film because of volume expanding during the oxidation of Zircaloy-4. The oxide film heaves due to compressive stress, which brings strain stress perpendicular to interface, the strain stress leads oxide film break and results in accelerating corrosion rate. The higher the concentration of LiOH aqueous solution is, the quicker the process is.

关 键 词：ZR-4合金 水化学 氧化膜 扫描电子显微镜 扫描探针显微镜 

分 类 号：TL341[核科学技术—核技术及应用]