新型三齿含膦配体的Ni(Ⅱ)配合物的合成和晶体结构  

Synthesis and Crystal Structure of a New Tridentate Ni(Ⅱ) Complex {Ni(H_2O)_3[Ph_2(o-Ph-N-C_7H_7N)]PO}Cl_2

作　　者：程林[1] 欧阳超琴[2] 杨玲[2] 

机构地区：[1]安徽师范大学化学与材料科学学院,芜湖241000 [2]昆明理工大学生物与化学工程学院,昆明650224

出　　处：《无机化学学报》2005年第1期70-72,共3页Chinese Journal of Inorganic Chemistry

摘　　要：A new tridentate Ni(Ⅱ) complex {Ni(H2O)3[Ph2(o-Ph-N-C7H7N)]PO}Cl2 was synthesized by the reaction of a new ligand Ph2(o-Ph-N-C7H7N)]PO with NiCl2 in C H3CH2OH. The complex was characterized by X-ray single crystal diffraction. The crystal structure of the complex belongs to monoclinic space group P21/n, a=1.25 9 28(9) nm, b=1.201 24(8) nm, c=2.039 03(14) nm, V=3.016 8(4) nm-3, Z=4, and R1= 0.047 1, wR2=0.120 5. And a molecular CH2Cl2 is filled in the crystal structure. CCDC: 241832.A new tridentate Ni(Ⅱ) complex {Ni(H2O)3[Ph2(o-Ph-N-C7H7N)]PO}Cl2 was synthesized by the reaction of a new ligand Ph2(o-Ph-N-C7H7N)]PO with NiCl2 in C H3CH2OH. The complex was characterized by X-ray single crystal diffraction. The crystal structure of the complex belongs to monoclinic space group P21/n, a=1.25 9 28(9) nm, b=1.201 24(8) nm, c=2.039 03(14) nm, V=3.016 8(4) nm-3, Z=4, and R1= 0.047 1, wR2=0.120 5. And a molecular CH2Cl2 is filled in the crystal structure. CCDC: 241832.

关 键 词：PO CH2O 新型 合成 Ni(Ⅱ) NiCl2 OH 配合物 晶体结构 配体 

分 类 号：O641.4[理学—物理化学] O614[理学—化学]