一个二核钒配合物的合成及晶体结构:NH_4[(V^(Ⅳ)O)_2(μ_2-O)(nta)_2][EuⅢ(H_2O)_9](英文)  

Synthesis and Crystal Structure of a Binuclear Vanadium Complex:NH_4[(V~ⅣO)_2( Ⅲ(H_2O)_9]

作　　者：张全争[1] 陈淑妹[1] 余雅琴[1] 何翔[1] 闫莹[1] 刘九辉[1] 许新江[1] 夏昌坤[1] 陈丽娟[1] 吴小园[1] 卢灿忠[1] 

机构地区：[1]中国科学院福建物质结构研究所结构化学国家重点实验室,福州350002

出　　处：《无机化学学报》2005年第1期101-104,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.902060402033307020303021);福建省自然科学基金资助项目(No.20002F0152002J006)

摘　　要：A binuclear vanadium complex NH4[(VⅣO)2( Ⅲ(H2O)9] wa s synthesized by reaction of NH3VO3, nitrilotriacetic acid and EuCl3 in one aque ous solution. The crystal X-ray analysis shows that the complex contains one bin uclear vanadium anion [(VⅣO)2( -and one [EuⅢ(H2O)9]3+ cation. T he molecules are built up to a three-dimensional supramolecular structure throug h hydrogen bonding. CCDC: 238716.A binuclear vanadium complex NH4[(VⅣO)2( Ⅲ(H2O)9] wa s synthesized by reaction of NH3VO3, nitrilotriacetic acid and EuCl3 in one aque ous solution. The crystal X-ray analysis shows that the complex contains one bin uclear vanadium anion [(VⅣO)2( -and one [EuⅢ(H2O)9]3+ cation. T he molecules are built up to a three-dimensional supramolecular structure throug h hydrogen bonding. CCDC: 238716.

关 键 词：二核配合物 钒配合物 合成 晶体结构 氮三乙酸 

分 类 号：O614.511[理学—无机化学] O641.4[理学—化学]