新的含有4-对甲基苯基-3,5-二(2-吡啶基)-1,2,4-三氮唑钴配合物的合成和晶体结构(英文)  

Synthesis and Crystal Structure of a New Cobalt (Ⅲ) Complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole

作　　者：朱敦如[1] 王作祥[2] 宋军[1] 李一志[3] 兰大艳[2] 

机构地区：[1]南京工业大学化学系,南京210009 [2]东南大学化学化工系,南京210096 [3]南京大学配位化学国家重点实验室配位化学研究所,南京210093

出　　处：《无机化学学报》2005年第1期128-132,共5页Chinese Journal of Inorganic Chemistry

基　　金：南京工业大学科研启动基金资助项目(No.51301031)

摘　　要：A new cobalt Ⅲ complex, [CoL2(NCS)2]·2CH2Cl2, [L=4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group P21/ c, a=0.867 40(17), b=1.453 9(3), c=1.781 9(4) nm, 18(3)The cobalt atom is in a distorted octahedral environment with two bidentate chelating L ligands in the equatorial plane and t wo NCS-ions in the axial positions. CCDC: 251658.A new cobalt Ⅲ complex, [CoL2(NCS)2]·2CH2Cl2, [L=4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group P21/ c, a=0.867 40(17), b=1.453 9(3), c=1.781 9(4) nm, 18(3)The cobalt atom is in a distorted octahedral environment with two bidentate chelating L ligands in the equatorial plane and t wo NCS-ions in the axial positions. CCDC: 251658.

关 键 词：钴配合物 吡啶基 甲基苯 三氮唑 晶体结构 苯基 CL2 合成 

分 类 号：O625.11[理学—有机化学] O614.812[理学—化学]