均苯三甲酸合成条件的研究  

Study of Synthetic Conditions of Trimesitinic Acid

作　　者：王心良[1] 蒋宗林[1] 陈江凌[1] 陈琳[1] 周关勇[1] 

机构地区：[1]西华师范大学化学化工学院,四川南充637002

出　　处：《西华师范大学学报（自然科学版）》2004年第4期426-428,共3页Journal of China West Normal University(Natural Sciences)

基　　金：四川省教育厅自然科学基金重点项目(No.2004A103).

摘　　要：以均三甲苯为原料制取均苯三甲酸,其产率偏低一直是困扰合成者的问题.作者分别从温度、酸碱性、溶剂和催化剂等影响因素出发,对实验条件进行了较全面的探索,得到了有规律性的结论,寻找到了提高产率的较好途径,并对这些影响因素进行了深入讨论.Trimesitinic acid, a special carboxylic acid, is usually synthesized from 1,3,5-trimethylbenzene by oxidation of KMnO_4 in based aqueous solution, but lower yield is a problem. This paper is trying to explore the synthetic conditions systematically in the aspects of temperature, pH value, solvent, phase-transfer catalysts, etc. ,respectively. The experiment obtains some practical conclusions and a better condition which could give a good product yield. The affecting factors have been fully disscused.

关 键 词：均三甲苯 均苯三甲酸 合成 

分 类 号：O625.511[理学—有机化学]