一种新的氟离子荧光识别主体2,3-二(2-吡咯酰胺)甲基喹喔啉的合成、结构及离子识别研究  

Synthesis, Crystal Structure and Ion Recognition of 2,3-Bis (2-pyrrole amide)methylquinoxaline as a Novel Fluoride Selective Fluorescent Chemosensor

作　　者：杨文智[1] 尹振明[1] 何家骐[1] 程津培[1] 

机构地区：[1]南开大学化学系元素有机化学国家重点实验室,天津300071

出　　处：《高等学校化学学报》2004年第12期2269-2272,共4页Chemical Journal of Chinese Universities

基　　金：国家重点基础发展规划项目 (批准号 :G2 0 0 0 0 7810 0 );国家自然科学基金 (批准号 :2 0 0 72 0 2 0 7)资助

摘　　要：设计并合成了 2 ,3 -二 ( 2 -吡咯酰胺 )甲基喹喔啉化合物 2 .通过 X射线单晶衍射研究了该化合物的固态结构 .分别利用荧光和紫外 -可见光谱技术研究了其对阴离子的识别 ,发现化合物 2能在 DMSO中对氟离子进行有效的选择性识别 ,主要的识别位点为吡咯 NH和酰胺In the last two decades, the research of the anion recognition has bloomed splendidly. The strong influence of the anion in the field of biological system, industry and every day life made the qualitative and quantitative research in anion recognition more and more important. After realizing the important role played by anions in biology and environment, various anions recognition hosts were synthesized. Herein, we report the synthesis of a quinoxaline based compound, namely 2,3-bis(2-pyrrole amide)methylquinoxaline(2) through seven steps reaction. The crystal structure of compound 2 was studied. The fluoride recognition propriety of compound 2 was studied by monitoring the perturbation of the UV-Vis and the fluorescent spectra of the host upon the addition of anion. The result show that compound 2 can recognize fluoride in DMSO efficiently, and the main recognition sites are pyrrole NHs and amide NHs.

关 键 词：2 3-二(2-吡咯酰胺)甲基喹喔啉 合成 晶体结构 氟离子识别 

分 类 号：O625[理学—有机化学]