四苯基卟啉及其金属配合物的裂解色谱研究  

Pyrolysis-Gas Chromatography of Tetraphenyl-porphyrin and Its Metallic Complexes

作　　者：徐正炎[1] 

机构地区：[1]中国科学院长春应用化学研究所,130022

出　　处：《色谱》1993年第4期225-227,共3页Chinese Journal of Chromatography

摘　　要：四苯基卟啉及其铁、锰等金属配合物是一类具有较大分子量、非挥发性的卟啉衍生物。由于结构和性能上的特点,这类物质成为有机合成中一种新型催化剂。关于这类物质的裂解研究尚未见有文献报道。本文用裂解色谱法(PGC)The thermal decomposition behaviors of tetra-phenylporphyrin(H2TPP) and its ferric and manganic complexes were studied by pyrolysis-gas chromato-graphy. The main pyrolysis products were separated and identified. The pyrolysis mechanism of H2TPP and its metallic complexes is discussed.

关 键 词：四苯基卟啉 金属络合物 裂解色谱 

分 类 号：O626.13[理学—有机化学]