烯烃氢甲酰化反应催化剂的研究进展  

Research Progress in Catalyst for Hydroformylation of Olefin

作　　者：张娴[1] 卫敏[1] 

机构地区：[1]北京化工大学理学院,北京100029

出　　处：《精细与专用化学品》2004年第23期7-9,共3页Fine and Specialty Chemicals

摘　　要：综述了烯烃氢甲酰化反应的催化剂体系 ,通过对发展较成熟的烯烃氢甲酰化均相催化体系缺点的分析 ,引入近 2 0年来发展起来的水溶性膦配体和过渡性金属配位生成的水 /有机两相催化体系 ,对其催化机理、优点和最新发展动态进行了评述 ;最后重点介绍了负载水相催化体系的组成、优点、水溶性配体和已报道的此类催化剂。The catalytic systems for hydroformylation of olefin were summarized. Through analysis of the disadvantages of homogeneous catalytic system, water/organics binary-phase catalytic system e.g. water soluble phosphine ligand and transitional metal complex, arising in recent 20 years were introduced, and the mechanism of catalytic reaction, merits and recent development trend were reviewed. Finally, the composition, advantages,water soluble ligand of supported aqueous-phase catalysis system and this kind of catalyst reported already was emphatically introduced

关 键 词：催化剂体系 烯烃 两相催化体系 水溶性膦配体 氢甲酰化反应 均相催化 催化机理 配位 水相 负载 

分 类 号：O643.3[理学—物理化学]