有机硼表面活性剂的合成及其应用研究  

Research on Synthesis and Application of Organoboron Based Surfactants

作　　者：庄严[1] 吕嘉冬[1] 吴瑞征[1] 王朝晖[1] 李金彩[1] 

机构地区：[1]北京市化学工业研究院,北京100084

出　　处：《精细与专用化学品》2005年第1期14-16,共3页Fine and Specialty Chemicals

基　　金：北京市自然科学基金资助项目 ;项目编号 :2 0 0 2 0 10。

摘　　要：以硼酸和甘油为起始原料 ,合成了几种以硼酸双甘油酯为中间体及环氧乙烷修饰的有机硼表面活性剂。通过红外光谱确定了产物的结构 ,并对有机硼表面活性剂的酸值、表面张力以及临界胶束浓度等性能进行了研究。最后重点探讨了有机硼表面活性剂在塑料抗静电领域的应用性能。Starting with boric acid and glycerin, several organoboron based surfactants using diglycerin borate as intermediate and modified with epoxyethane were synthesized. Their structures were confirmed by IR, and the properties of these surfactants such as acid number, interfacial tension, and critical micelle concentration and so on were studied. Finally, organoboron surfactants used in plastics for anti static application was discussed emphatically.

关 键 词：表面活性剂 合成 起始原料 硼酸 中间体 有机 环氧乙烷 应用性能 应用研究 抗静电 

分 类 号：TQ423[化学工程]