发光配合物1,2-二(2-吡啶甲酰胺基)苯锌的研究  

Luminescent 1,2-Bis(2-pyridinecarboxamido)benzene Zinc(Ⅱ) Complexes

作　　者：叶开其[1] 吴英[1] 郭建华[1] 孙迎辉[1] 王悦[1] 

机构地区：[1]吉林大学超分子结构与材料教育部重点实验室,长春130012

出　　处：《高等学校化学学报》2005年第1期93-96,共4页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:50225313);国家重点基础研究发展规划项目(批准号:2002CB613401);吉林省科技厅研究项目(批准号:20010301-2)资助

摘　　要：合成了发光配合物 1 ,2 -二 (2 -吡啶甲酰胺基 )苯锌 (1 )及其双分子 -4,4′-联吡啶复合物 (2 ) .用 X射线单晶衍射分析方法得到了配合物 2的单晶结构 .该晶体属三斜晶系 ,P1空间群 ,晶胞参数为 a=0 .962 5 1 (6)nm,b=1 .5 0 1 2 2 (9) nm,c=1 .642 5 2 (1 2 ) nm,α=1 0 6.95 8(2 )°,β=1 0 5 .3 62 (3 )°,γ=1 0 2 .978(2 )°,V=2 .0 685 (2 ) nm3,Z=2 ,Dc=1 .5 63 g/cm3,F(0 0 0 ) =1 0 0 0 ,R1 =0 .0 3 67,w R2 =0 .0 898.研究表明 ,晶体 2由 1个 4,4′-联吡啶通过配位键连接 2个化合物 1分子构成 .晶体 2是由沿晶体学 b和 c轴方向的一维分子柱堆积而成 .考察了配合物 1的发光性质 ,配合物 1可作为发光材料效率很高的电致发光器件制备 .Luminescent complexes Zn(bpb)(1) and Zn 2(bpb) 2(bpy)(2)(bpb=1,2-bis(2-pyridinecarboxamido)benzne, bpy=4,4′-bipyridine) were synthesized and complex 2 was characterized by single crystal X-ray diffraction. Crystal data for Complex 2: monoclinic, space group P1, a=0.962 51(6) nm, b=1.501 22(9) nm, c=1.642 52(12) nm, α=106.958(2)°, β=105.362(3)°, γ=102.978(2)°, V=2.068 5(2)nm3, Z=2, D c=1.563 g/cm3, F(000)=1000, R 1=0.036 7, wR 2=0.089 8. Complex 2 was formed by two molecules of complex 1, which were linked by a bpy ligand through coordination bonds. In the solid of complex 2, there were face-to-face intermolecular π-π stacking interactions resulting in the formation of one-dimensional molecular chains, which oriented along crystallographic b and c axis, respectively. The photo and electro-luminescent properties of complex 1 were characterized. Complex 1 was employed as an emitting material to fabricate electroluminescent device with a high efficiency.

关 键 词：发光材料 1 2-双(吡啶酰胺基)苯配合物 电致发光 

分 类 号：O641[理学—物理化学]