Ni(phen)(H_2O)(V_2O_6)的水热合成和晶体结构(英文)  

Hydrothermal Synthesis and Crystal Structure of Ni(phen)(H_2O)(V_2O_6)

作　　者：周泊[1] 史发年[1] 王静梅[2] 陈民勤[2] 

机构地区：[1]南京师范大学化学与环境科学学院,南京210097 [2]复旦大学分析测试研究中心,上海200433

出　　处：《无机化学学报》2005年第2期217-220,共4页Chinese Journal of Inorganic Chemistry

摘　　要：A novel compound Ni(phen)(H2O)(V2O6) has been hydrothermally synthesized and structurally determined to be a two-dimensional compound, which contains {V2O6}n2n- chains interconnected by nickel(II) complexes via oxygen atoms. The crystallographic data measured by single-crystal X-ray diffraction analysis are as follows: C12H10N2NiO7V2, Mr=454.81, monoclinic, space group P21 / c, a=0.784 6(3), b=2.103 6(8), c=0.942 3(4) nm, β=112.872(5)°, V=1.433 0(10) nm3, Z=4, Dc=2.104 Mg·m-3, μ(Mo Kα)=2.615 mm-1, F(000)=904, T=298(2) K, 4 480 reflections collected, 2 470 independent (Rint=0.032 2), the final R=0.058 4 and wR2=0.145 7 for 2 303 observed reflections with I>2σ(I). CCDC: 192520.A novel compound Ni (phen)(H2O)(V2O6) has been hydrothermally synthesized and structurally determined to be a two-dimensional compound, which contains (V2O6](n)(2n-) chains interconnected by nickel(II) complexes via oxygen atoms. The crystallographic data measured by single-crystal X-ray diffraction analysis are as follows: C12H10N2NiO7V2, M-r=454.81, monoclime, space group P2(1)/c, a=0.784 6(3), b=2.103 6(8), c=0.9423(4) nm, beta= 112.872(5)degrees, V=1.433 0(10) nm(3), Z=4, D-c=2.104 Mg.m(-3), mu(Mo Kalpha)=2.615 mm(-1), F(000)=904, T=298(2) K, 4 480 reflections collected, 2 470 independent (R-int=0.032 2), the final R=0.058 4 and wR(2)=0- 145 7 for 2 303 observed reflections with I>2sigma(I). CCDC: 192520.

关 键 词：有机-无机杂合物 钒氧化物 水热合成 晶体结构 Ni(phen)(H2O)(V2O6) 

分 类 号：O614.511[理学—无机化学] O641.4[理学—化学]