流化床中RDF焚烧时CO、SO_2和HCl的生成  

Formation of CO, SO_2 and HCl during RDF incineration in a fluidized bed

作　　者：魏小林[1] 盛宏至[1] 刘典福[1] 田文栋[2] 秦成[2] 肖云汉[2] 

机构地区：[1]中国科学院力学研究所,北京100080 [2]中国科学院工程热物理研究所,北京100080

出　　处：《环境科学学报》2005年第1期34-38,共5页Acta Scientiae Circumstantiae

基　　金：国家自然科学基金(50376068)

摘　　要：在非均匀布风流化床中进行了垃圾衍生燃料(RDF)与煤的混烧试验,测量了H2O、CO、CO2、NO、N2O、HCl、SO2等污染物质的排放特性.结果表明与单纯燃烧RDF相比,混烧时的CO生成量大大下降;SO2生成浓度较低,而HCl的生成量比单纯烧煤时明显增加.The refuse-derived fuels-RDF has the advantage of high heating value and is easily combusted. The potential application of RDF is co-firing with coal and instead of some coal in the boiler. The heating value of RDF may attain 24MJ·kg^(-1), similar with that of coal. Due to the high content of volatiles in RDF (more than 70%), a large quantity of volatiles is likely to release during RDF incineration. If the pollutant emissions can not be controlled very well, the limit of environmental standard will not be guaranteed. On the other hand, the contents of harmful elements in coal or RDF are very different. For coal, the content of nitrogen or sulfur is higher and the content of chlorine is very lower, on contrary, to those in RDF (normally with a higher content of chlorine and lower sulfur content). Therefore, during co-firing RDF with coal, the interaction of pollutants NO_x, SO_x, HCl and ash may occur and the combustion properties of co-firing cannot be predicted only by the results of burning pure coal or pure RDF. The internally circulating fluidized bed (ICFB) is applied to investigate the pollutant emissions during co-firing RDF with coal. In the ICFB, the air plenum is separated as two equal boxes. Then the primary air separately enters the bed from air boxes with high or low air velocity. Unevenly distributed fluidized air induces a large-size internal circulating flow of solid particles in the dense bed which may improve the properties of lateral diffusion. The cross section of the furnace is 500mm×240mm in the dense phase zone and 800mm×280mm in the freeboard. The total height of the furnace is 4500mm. Concentrations of pollutants in the flue gas were measured by Fourier Transform Infrared (FTIR) spectrometry (Gasmet DX-3000). In the tests, the concentrations of the species, such as H_2O, CO, CO_2, NO, NO_2, N_2O, HCl, SO_2, CH_4, C_2H_2, C_2H_4, C_2H_6 and C_6H_6 were measured online with 2% error. The concentration of oxygen was measured by an oxygen analyzer (TEMET 19) with 0.2% error. The result

关 键 词：SO2 焚烧 RDF 垃圾衍生燃料 混烧 流化床 污染物质 CO 量比 生成量 

分 类 号：X705[环境科学与工程—环境工程] X701