填料塔中碳酸钾/哌嗪混合吸收液脱除CO_2的体积传质系数  

Volumetric mass transfer coefficients of dilute CO_2 absorption into mixtures of potassium carbonate and piperazine in packed column

作　　者：骆培成[1] 焦真[1] 张志炳[1] 

机构地区：[1]南京大学化工系,江苏南京210093

出　　处：《化工学报》2005年第1期53-57,共5页CIESC Journal

基　　金：国家"985"工程资助项目~~

摘　　要：The process of removing dilute CO 2 from air by using the mixtures of K 2CO 3 and piperazine (PZ) was conducted in a random packed tower at 25 ℃.The results showed that PZ increased the absorption rate of CO 2 into aqueous K 2CO 3 much more effectively than MEA or DEA. The volumetric overall mass transfer coefficient (K Ga) of dilute CO 2 absorption into K 2CO 3/PZ was measured.The K Ga value was evaluated over the ranges of main operating variables: the concentration of CO 2 in inlet gas, gas flow rate, liquid loading, CO 2 loading in liquid phase,and the concentrations of K 2CO 3 and PZ. The test showed that K Ga could be remarkably improved by increasing liquid loading and the concentration of PZ, and decreasing the concentration of CO 2 in inlet gas, as well as the gas flow rate and CO 2 loading in liquid phase.The process of removing dilute CO2 from air by using the mixtures of K2CO3 and piperazine (PZ) was conducted in a random packed tower at 25°C. The results showed that PZ increased the absorption rate of CO2 into aqueous K2CO3 much more effectively than MEA or DEA. The volumetric overall mass transfer coefficient (KGa) of dilute CO2 absorption into K2CO3/PZ was measured. The KGa value was evaluated over the ranges of main operating variables: the concentration of CO2 in inlet gas, gas flow rate, liquid loading, CO2 loading in liquid phase, and the concentrations of K2CO3 and PZ. The test showed that KGa could be remarkably improved by increasing liquid loading and the concentration of PZ, and decreasing the concentration of CO2 in inlet gas, as well as the gas flow rate and CO2 loading in liquid phase.

关 键 词：二氧化碳 碳酸钾 哌嗪 填料塔 体积总传质系数 

分 类 号：TQ028[化学工程]