胺蒽类有机电致发光材料的合成和发光性能的研究  

Study on Synthesis of Organic Light Emitting Diode Materials of Aminoanthrancenes and Their Light Emitting Property

作　　者：余明新[1] 陈晓航[1] 郑建鸿[2] 

机构地区：[1]浙江大学化学系,杭州310027 [2]台湾清华大学化学系,新竹30043

出　　处：《有机化学》2005年第2期218-221,共4页Chinese Journal of Organic Chemistry

基　　金：教育部留学回国人员基金(No.200314)资助项目.

摘　　要：芳基伯胺与芳基溴在Pd(dba)2/P(t-Bu)3催化下于80℃甲苯溶液中反应生成芳基仲胺,芳基仲胺再与溴代蒽在Pd(OAc)2/P(t-Bu)3催化下于120℃邻二甲苯溶液中反应生成蒽类芳胺有机电致发光材料,产物的结构经HNMR,113CNMR,C(DEPT),MS(HREI和EI)光谱所证实.用UV-vis,PL,DSC测定了蒽类芳胺化合物的发光性能.The primary arylamines reacted with arylhalides to give the secondary arylamines by the catalysis of Pd(dba)(2)/P(t-Bu)(3) at 80 V in toluene. The secondary arylamines reacted with bromoanthrancenes to afford the organic light emitting diode materials of aminoanthrancene type by the catalysis of Pd(OAc)(2)/P(t-BU)(3) at 120 degreesC in o-xylene. The product structures were demonstrated by H-1 NMR, C-13 NMR, C-13 (DEPT) and HRMS spectra. Physical properties were examined by UV-Vis, PL and DSC spectra.

关 键 词：钯催化 芳胺 胺葸 三叔丁基磷 有机电致发光材料 发光性能 

分 类 号：O625[理学—有机化学]