环己二胺类手性席夫碱配体的合成与表征  

Preparation and Characterization of Five Chiral Schiff-ligands Derived from 1,2-Diaminocyclohexane

作　　者：张英菊[1] 吕小兵[1] 王辉[1] 梁斌[1] 

机构地区：[1]大连理工大学精细化工国家重点实验室,辽宁大连116012

出　　处：《合成化学》2005年第1期64-66,共3页Chinese Journal of Synthetic Chemistry

摘　　要：以(R,R)1,2环己二胺为手性源,同水杨醛及带有叔丁基,溴或硝基的取代水杨醛反应合成了5个手性席夫碱配体。其结构经1HNMR,13CNMR,IR和MS表征,并测定了其熔点和比旋光度。Five chiral Schiff-ligands were prepared from (R,R)-1,2-diaminocyclohexane and salicyaldehyde or t-butyl-, bromo-, nitro-substituted salicyaldehydes. Their structures were characterized by 1H NMR, ~13 C NMR, IR and MS.The melt points and specific optical rotations of the ligands were determined.

关 键 词：环己二胺 手性 席夫碱配体 水杨醛 表征 

分 类 号：O621.3[理学—有机化学]