三苯基锡(IV)哌啶氨荒酸酯的合成及结构研究  

Synthesis and Crystal Structure of Triphenyltin(Ⅳ) Dithiopiperidylcarbamate

作　　者：尹汉东[1] 王传华[1] 马春林[1] 房海霞[1] 

机构地区：[1]聊城大学化学系,山东聊城252059

出　　处：《分析科学学报》2005年第1期57-59,共3页Journal of Analytical Science

基　　金：国家自然科学基金(No.20271025);山东省自然科学基金(Z2001B02)

摘　　要：利用三苯基氯化锡和哌啶氨荒酸钠反应,合成了三苯基锡(IV)哌啶氨荒酸酯。通过元素分析、红外光谱和核磁共振氢谱对其结构进行了表征。用X 射线单晶衍射测定了该化合物的晶体结构。结果表明,化合物中锡原子呈五配位畸变三角双锥构型。The compound of triphenyltin(IV) dithiopiperidylcarbamate has been synthesized by the reaction of Ph_(3)SnCl with dithiopiperidylcarbamate and was characterized by elemental analysis, UV, IR and^(1)H NMR. The crystal structure has been determined by X-ray single crystal diffraction, and it shows a distorted tigonal bipyramidal configuration with five-coordination for the central tin atom.

关 键 词：三苯基锡(IV)氨荒酸酯 合成 晶体结构 

分 类 号：O655.4[理学—分析化学] O641[理学—化学]