Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)、Ag(Ⅰ)和Pb(Ⅱ)的2,5-噻吩二甲醛双缩邻氨基苯酚希夫碱配合物的合成及性质的研究  

SYNTHESES AND PROPERTIES OF 2,5-BIS-(2-HYDROXYANILINO) METHYLENYL THIOPHENE COMPLEXES OF COBALT(Ⅱ), NICKEL(Ⅱ), COPPER(Ⅱ),SILVER(Ⅰ) AND LEAD(Ⅱ)

作　　者：张文昭[1] 周彦同 余宝源 

机构地区：[1]南京大学化学系,南京210008 [2]江苏广播电视大学

出　　处：《无机化学学报》1993年第2期216-220,共5页Chinese Journal of Inorganic Chemistry

摘　　要：合成了新的Schiff碱2,5-噻吩二甲醛双缩邻氨基苯酚及其与钴(Ⅱ)、镍(Ⅱ)、铜(Ⅱ)、银(Ⅰ)和铅(Ⅱ)的配合物,经元素分析、红外振动光谱和热重-差热分析表征,并测定了磁化率和电导率,确定了这些配合物的组成、磁性、稳定性和可能的空间构型.2,5-bis-(2-hydroxy anilino) mcthylenyl thiophcnc C18H14O2N2S and its complexes with cobalt(Ⅱ), nickel(Ⅱ), coppcr(Ⅱ), silver(Ⅰ) and lead(Ⅱ?) were synthesized. The measurement of elemental analysis, electrical conductivity, magnetic susceptibility, infrared spectra, electronic spectra, thcrmogravimetric (TG) and differential thermal analyses (DTA) were carried out. The relationship between their structures and properties are also studied. These complexes arc stable at the room temperature.

关 键 词：配合物 H2L 钴 镍 铜 银 

分 类 号：O614.8[理学—无机化学]